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J. Korean Ceram. Soc. > Volume 62(3); 2025 > Article
Journal of the Korean Ceramic Society 2025;62(3): 553-566.
doi: https://doi.org/10.1007/s43207-025-00481-6
A multistage de-binding approach for material extrusion-based additively manufactured fabricated zirconia ceramics
Subham Kumar Pandey, Amit Rai Dixit
Department of Mechanical Engineering, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India
Correspondence  Amit Rai Dixit ,Email: amitraidixit@iitism.ac.in
Received: August 6, 2024; Revised: November 15, 2024   Accepted: January 19, 2025.  Published online: February 18, 2025.
ABSTRACT
Material extrusion-based fused filament fabrication (FFF) offers a straightforward and cost-effective method for ceramic additive manufacturing (AM) compared to other techniques. It involves FFF printing, de-binding, and sintering to create intricate ceramic components. De-binding is crucial and time-intensive in this process. Various partial de-binding methods remove binders before thermal de-binding (TDB), ensuring defect-free ceramics. This study explores multistage de-binding for three mol% yttria-stabilized zirconia ceramic filaments. Solvent de-binding (SDB) and Wick de-binding (WDB) were tested alongside TDB. Two-stage de-binding methods (SDB + TDB, WDB + TDB) and a three-stage method (SDB + WDB + TDB) were compared. WDB showed cracks and distortion, indicating suboptimal results in WDB + TDB. The three-stage approach (SDB + WDB + TDB) removed 99.52% of polymer binders, 1.93% more than the two-stage (SDB + TDB). Densification was comparable: 99.31% (two-stage) and 99.48% (three-stage), highlighting the three-stage method's potential for superior binder removal without compromising density.
Key words: Multistage de-binding · Material extrusion · Zirconia
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