유기물로 수식된 몬트모릴로나이트 제조 및 특성조사 |
김재명, 유중환, 최의석, 이성민, 김형태 |
요업기술원 도자.구조세라믹본부 소재팀 |
Synthesis and Characterization of Organo-modified Montmorillonite by Ion-exchange Method |
Jae-Myung Kim, Jung-Whan Yoo, Eui-Seok Choi, Sung-Min Lee, Hyung-Tae Kim |
Material Team, Whiteware.Structural Ceramics Center, Korea Institute of Ceramic Engineering and Technology |
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ABSTRACT |
Hydrophilicity and hydrophobicity of pottery bodies can be controlled via chemical substitution of layered clay with hydrophilic and hydrophobic organics. In this study, organo-clay nanocomposites were prepared by ion-exchange of montmorillonite with dodecylamine and hexadecylamine, respectively. Substitution sites of organics and the interval changes of layered materials are characterized by FT-IR and WAXD and organics amounts loaded and water comtents contained by C/S analysis and TG-DSC. The organics were selectively intercalated so that increase layer interval from 12${AA}; to;16{AA}$. Organo-modified clay is changed to more hydrophobic comparing to clay itself. |
Key words:
Clay, Modification, Organics, Montmorillonite, Dodecylamine, Hexadecylamine |
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