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J. Korean Ceram. Soc. > Volume 40(4); 2003 > Article
Journal of the Korean Ceramic Society 2003;40(4): 354.
doi: https://doi.org/10.4191/kcers.2003.40.4.354
Microwave Dielectric Characteristics of Aluminum Magnesium Tantalate Based High Q Ceramics
Ji-Won Park, Hwack-Joo Lee1, Seok-Jin Yoon, Hyun-Hai Kim
Thin Film Materials Research Center, Korea Institute of Science and Technology
1New Materials Evaluation Center, Korea Research Institute of Standard and Science
ABSTRACT
The microwave dielectric characteristics of (1-x)(Al$_$$frac{1}{2}$/Ta$_$$frac{1}{2}$/)O$_2$-x(Mg$_$1/3/Ta$_$2/3/)O$_2$ (0$leq$x$leq$1.0) ceramics were investigated by crystalstructure, variations of ionic polarizability, and microstructures. As x increased, (1-x)(Al$_$$frac{1}{2}$/Ta$_$$frac{1}{2}$/)O$_2$-x(Mg$_$1/3/Ta$_$2/3/)O$_2$ transformed to tetragonal structure. Because the ionic radius of (Mg$_$1/3/Ta$_$2/3/)$^$4+/was slightly bigger than one of (Al$_$$frac{1}{2}$/Ta$_$$frac{1}{2}$/)$^$4+/, the cell parameters increased with increase of (Mg$_$1/3/Ta$_$2/3/)O$_2$concentration and coincided with prediction of the molecular additivity rule. As x increased, the compositions revealed ordered phase and were of single phase above 60 mol%. The increase of the ordered phase and grain size enhanced the Q and when ordering was completed at x over 0.6, the grain size was major factor for the increase in the a. Though the grain size increased, however, the porosity deteriorated the q. Therefore, the a depended on the order/disorder, the porosity, and the grain size in regular order.
Key words: Microwave dielectric materials, Dielectric constant, Quality factor, Ionic polarizability, Ordering
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