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Journal of the Korean Ceramic Society 2000;37(2): 128. |
리튬이온전지용 부극재료인 페트롤리엄 및 콜타르 피치 카본의 전지반응 특성에 관한 연구 |
박영태, 유광수, 김정식 |
서울시립대학교 재료공학과 |
Study on the Characteristics of Cell Reactions for Petroleum- and Coal Tar Pitch-based Carbons as a Negative Electrode for Li-iion Batteries |
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ABSTRACT |
In this work, soft carbons produced by pyrolysis of petroleum and coal-tar pitch were used as the negative electrode for Li-ion batteries. We studeid the charge/discharge capacity and the interfacial reaction of these electrodes by constructing a half cell. Charge/discharge property was studied by a constant-current step and the interfacial reaction between the electrolyte and the surface of a carbon electrode was studied by the cyclic voltammetry. The initial charge/discharge capacity for the coal-tar pitch carbon increased exceedingly with the heat treatment temperature. On hte other hand, the capacity of the petroleum pitch carbon increased with temperature up to 1000$^{circ}C$, thereafter decreased continuously. While the charge capacity decreased with the cycle number, the reversibility increased above 90%. In addition, the thermal stability and crystallization of petroleum and coal-tar pitches were analyzed by TGA and XRD, respectively. |
Key words:
Li-ion battery, Carbon electrode, Electrochemical properties |
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