Effect of  Fe2+/Fe3+ Ratio on the Crystallization of the Scoria Glass (CaO-MgO-Al2O3-SiO2 System)

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J. Korean Ceram. Soc. > Volume 26(5); 1989 > Article

Journal of the Korean Ceramic Society 1989;26(5): 705.

Scoria 유리(CaO-MgO-Al2O3-SiO2계)의 결정화에 미치는 Fe2+/Fe3+비 효과

최병현, 지응업¹

아주대학교
¹동양공업전문대학

Effect of Fe2+/Fe3+ Ratio on the Crystallization of the Scoria Glass (CaO-MgO-Al2O3-SiO2 System)

ABSTRACT

The glass-ceramics was prepared with the scoria(CaO-MgO-Al2O3-SiO2 system) of the locally occurring volcanic ejecta containing 10-13w/o of (FeO＋Fe2O3) by melting at 140$0^{circ}C$ for 4 hours and thermally treated for nucleation and crystallization. The sucrose was added to the scoria to adjust the Fe2+/Fe3+ ratio during the melting process. The addition of 1-2w/o of sucrose showed the glass-ceramics body with the finest particle developed and dispersed over the entire range. It is concluded that the impurity content of iron oxide and titanium oxide play the most-influencial effect on the crystallization. When 1-2w/o of sucrose was added to the scoria, the value of Fe2+/Fe3+ ratio was 0.93-1.32 and showed the best result of crystallization. The nucleation temperature and time were calculated by the measurements of exothermic peak temperatures of DTA for quenched and thermally treated glasses. The nucleation temperature of scoria glass without the addition of sucrose was estimated as 75$0^{circ}C$, but the addition of sucrose by 2w/o showed the nucleation temperature 6$25^{circ}C$. The nucleation time was calculated with the same DTA curves. The nucleation times estimated were about 150min. for both of glasses without and with sucrose added. Finally, the activation energies for crystallization were calculated with the DTA data. The calculated activation energies were 143 Kcal/mole for the glass without addition of sucrose and 90Kcal/mole, 87Kcal/mole, 85Kcal/mole and 71Kcal/mole for the glasses of 1w/o, 2w/o, 3w/o and 4w/o addition respectively.