The Effects of Microstructures and Some Additives (CoO and <TEX>$Al_2O_3$</TEX>) on the Magnetic Properties of Mn-Zn Ferrite

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J. Korean Ceram. Soc. > Volume 16(3); 1979 > Article

Journal of the Korean Ceramic Society 1979;16(3): 142.

미세조직 및 첨가성분 (CoO와 $Al_2O_3$)이 Mn-Zn Ferrite의 자기적 성질에 미치는 영향

변수일, 장승현

한국과학원 재료공학과

The Effects of Microstructures and Some Additives (CoO and $Al_2O_3$) on the Magnetic Properties of Mn-Zn Ferrite

ABSTRACT

The effects of microstructures and some additives $(CoO and Al_2O_3$) on the magnetic properties such as initial permeability, $mu$-T curve, coercive force, and magnetic induction of MnZn ferrites have been studied. The powder was prepared by Hot Petroleum Drying Method. The basic composition of MnZn ferrites was 25.5mole % MnO, 22.0 mole% ZnO, 52.5 mole% $Fe_2O_3$. CoO in a concentration range from 0.05 to 0.5 mole% and $Al_2O_3$ from 2.5 to 7.5 mole% were added. Sintered density increased up to 97.5% of theoretical density. Permeability increased as average grain size increased, and that coercive force decreased as average grian size increased. Magnetic induction increased as sintered density increased. The variation of initial permeability with temperature in a temperature range from 0$^{circ}$ to $60^{circ}C$ was lowered (a flatter $mu-T$ curve) as sintering temperature decreased. The compensation temperature To ofmagnetocrystalline anisotropy constant K1 and initial permeability varied with the species and amount of additives. When 0.05 mole% CoO was added to the basic composition, initial permeability at $15^{circ}C$ increased from 5200 to 5900. The variation ofinitial permeability with temperature in a temperature range from 0^{circ}to $60^{circ}C$ was smaller (a flatter $mu$-T curve) than that of the basic composition of Mn Zn ferrites. When 2.5 mole% $Al_2O_3$ was added, initial permeability at $15^{circ}C$ decreased from 5200 to 3000. But the variation of initial permeability with temperature in a temperature range from 0$^{circ}$to $60^{circ}C$ was smaller (a flat ter $mu-T$ curve) than when 0.05 mole% CoO was added. Experimental results showed that the conditions necessary for the occurrence of a very high permeability and a flat $mu$-T curve were controversial even in a temperature range from $0^{circ}$to $60^{circ}C$.