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J. Korean Ceram. Soc. > Volume 45(8); 2008 > Article
Journal of the Korean Ceramic Society 2008;45(8): 459.
doi: https://doi.org/10.4191/kcers.2008.45.8.459
P2O5-SnO2계 유리에서 P2O5를 B2O3로 치환첨가 시 구조와 물성에 미치는 영향
최병현, 지미정, 안용태, 고영수, 이영훈1
요업(세라믹)기술원 전자소재팀
Effects of Substituting B2O3 for P2O5 on the Structure and Properties of P2O5-SnO2 Glass Systems
Byung-Hyun Choi, Mi-Jung Ji, Yong-Tae An, Young-Soo Ko, Young-Hun Lee1
Electric Materials Laboratory, Korea Institute of Ceramics Engineering and Technology
1Samsung SDI
$P_2O_5-SnO_2$ system $0.5SnO_2-xP_2O_5-(0.5-x)B_2O_3$(x=0.1, 0.2, 0.3, 0.4, 0.5) glasses have been prepared for Pb-free low temperature glass frit. A investigation about the effect of $B_2O_3$ substitution on properties of $P_2O_5$ glasses, including glass structure properties, thermal properties, and mechanical properties was presented. Substance that is responsible for in moisture absorption existing circumstances supposes by phosphate, and excess moisture tolerance that state funeral's structure is improved breaking does not affect in state funeral bond that only most single bond remains, and can know that does not suffer big impact in boric oxide anomaly present state. This phenomenon estimates that connect with structure change. It is thought according to link this result the phosphoric acid happened structural change. $B_2O_3$ displacement quantity 0.3 mole put out $BO_4$ structures, but above 0.3 mole it changed with the case $BO_3$ structure which it displaces.
Key words: $SnO_2-P_2O_5$ glass system, Pb-free, FT-IR, $B_2O_3$ substitution
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