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J. Korean Ceram. Soc. > Volume 44(10); 2007 > Article
Journal of the Korean Ceramic Society 2007;44(10): 537.
doi: https://doi.org/10.4191/kcers.2007.44.1.537
Microwave Dielectric Properties of 0.95Ca0.85Nd0.1TiO3−0.05LnAlO3 (Ln=Sm, Dy, Er) Ceramics
Eung Soo Kim, Chang-Jun Jeon
Department of Materials Engineering, Kyonggi University
ABSTRACT
Microwave dielectric properties of $0.95 Ca_{0.85}Nd_{0.1}TiO_3-0.05LnAlO_3$ (Ln=Sm, DH, Er) were investigated as a function of sintering temperature and lanthanide ion type. A single perovskite phase with an orthorhombic structure was obtained throughout the entire range of composition. The dielectric constant (K) was dependent upon the dielectric polarizabilities and the B-site bond valence in the $ABO_3$ perovskite structure. The quality factor (Qf) of the specimens with $ErAlO_3$ was smaller than those with $SmAlO_3;and/or;DyAlO_3$ due to the smaller grain size. The temperature coefficient of resonant frequency (TCF) could be controlled from $107.28ppm/^{circ}C$ at Ln=Sm to $87.23ppm/^{circ}C$ at Ln=Er due to the changes of B-site bond valence in the $ABO_3$ perovskite structure.偹Η⨀⣎袥Ā倀좔ﺖ⨀ȀᘀĀ꡹Η⨀삎᎞Ā倀悔ﺖ⨀ȀᘀĀzΗ⨀냔袥紅倀ﺖ⨀ē Ā塺Η⨀ᢏﺖ⨀က倀邓ﺖ⨀ଐကĀ炏ﺖ⨀胋袥Ȁ倀“ﺖ⨀ȀᘀĀࡻΗ⨀烑袥Ā倀颒ﺖ⨀ȀᘀĀ恻Η⨀炏᎞Ā倀をﺖ⨀ȀᘀĀ롻Η⨀ₐ᎞Ā倀좑ﺖ⨀ȀᘀĀၼΗ⨀ᣓ袥Ā倀悑ﺖ⨀ȀᘀĀ桼Η⨀ꃓ袥Ā倀ﺖ⨀ȀᘀĀ쁼Η⨀뢈᎞Ā倀梐ﺖ⨀ȀᘀĀ᡽Η⨀儒돀Η⨀ꡩ
Key words: $Ca_{0.85}Nd_{0.1}TiO_3$, $LnAlO_3$(Ln=Sm, Dy, Er), Bond valence, Microwave Dielectric properties
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