Synthesis of Powder of the System Si-Al-O-N from Alkoxides II. Properties of Powders and Sintered Ceramics of Si3N4 and <TEX>$beta$</TEX>-Sialon Prepared from Alkoxides

,; ,; ,; ,

J. Korean Ceram. Soc. > Volume 26(2); 1989 > Article

Journal of the Korean Ceramic Society 1989;26(2): 201.

알콕사이드로부터 Si-Al-O-N계 분말합성 II. 알콕사이드로부터 합성한 Si3N4 및 $beta$-Sialon의 분말 및 소결체의 특성

이홍림, 전명철

연세대학교 공과대학 요업공학과

Synthesis of Powder of the System Si-Al-O-N from Alkoxides II. Properties of Powders and Sintered Ceramics of Si3N4 and $beta$-Sialon Prepared from Alkoxides

ABSTRACT

Fine Si-Al-OH coprecipitate powders were prepared from Si- and Al-alkoxides by the hydrolysis method. $beta$-Sialon powder was obtained from prepared Si-Al-OH coprecipitate by the simultaneous reduction and nitridation method. The syntehsized Sialon powder was pressureless sintered at 175$0^{circ}C$ for 90 min in N2 atmosphere. The characterization of the Sialon powder was performed with XRD, BET, SEM, TEM and particle size analysis. The sinterability and mechanical properties of sintered bodies were investigated in terms of relative density, M.O.R., fracture toughness, hardness and the morphology of microstructure. The highest values of their mechanical properties were obtained for the $beta$-Sialon ceramics at Z=1 and those values are as follows : M.O.R., KIC and HV of $beta$-Sialon ceramics(Z=1) are 499.1 MPa, 5.9MN/m3/2 and 18.7GPa, respectively.