짧은 섬유상간의 접합을 가진 Silicon Carbide Web 복합재료의 분율별 열전도 거동 |
김태언, 배진철1, 조광연1, 이동진1, 설용건2 |
연세대학교 신에너지전지융합기술 협동과정 1한국세라믹기술원 나노 IT 융합센터 에코복합센터 2연세대학교 화공생명공학과 |
Thermal Conducting Behavior of Composites of Conjugated Short Fibrous-SiC Web with Different Filler Fraction |
Tae-Eon Kim, Jin Chul Bae1, Kwang Yeon Cho1, Dong Jin Lee1, Yong-Gun Shul2 |
New Energy and Battery Engineering, Yonsei University 1Division of Nano IT Convergence Center and Eco-composite Center, KICET 2Department of Chemical and Biomolecular Engineering, Yonsei University |
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ABSTRACT |
Silicon carbide(SiC) exhibits many unique properties, such as high strength, corrosion resistance, and high temperature stability. In this study, a SiC-fiber web was prepared from polycarbosilane(PCS) solution by employing the electrospinning process. Then, the SiC-fiber web was pyrolyzed at $1800^{circ}C$ in argon atmosphere after it was subjected to a thermal curing. The SiC-fiber web (ground web)/phenolic resin (resol) composite was fabricated by hot pressing after mixing the SiC-fiber web and the phenolic resin. The SiC-fiber web composition was controlled by changing the fraction of filler (filler/binder = 9:1, 8:2, 7:3, 6:4, 5:5). Thermal conductivity measurement indicates that at the filler content of 60%, the thermal conductivity was highest, at 6.6 W/mK, due to the resulting structure formed by the filler and binder being closed-packed. Finally, the microstructure of the composites of SiC-fiber web/resin was investigated by FE-SEM, EDS, and XRD. |
Key words:
Silicon carbide, Polycabosilane, Electrospinning, Composites, Thermal conductivity |
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